Stainless steel resists corrosion primarily due to the presence of chromium, which constitutes at least 10.5% of its composition. When exposed to oxygen, chromium forms a thin, stable layer of chromium oxide on the surface of the steel. This passive film is highly adherent and self-repairing, meaning that if the surface is scratched or damaged, the chromium oxide layer quickly reforms in the presence of oxygen, maintaining the protective barrier.
The passive layer prevents further oxidation and corrosion by blocking oxygen and moisture from reaching the underlying metal. This is in contrast to ordinary steel, which forms iron oxide, or rust, that flakes off and exposes fresh metal to further corrosion.
Other alloying elements, such as nickel, molybdenum, and nitrogen, can enhance the corrosion resistance of stainless steel. Nickel stabilizes the austenitic structure, improving toughness and resistance to acidic environments. Molybdenum increases resistance to pitting and crevice corrosion, particularly in chloride-rich environments like seawater. Nitrogen enhances mechanical strength and further improves resistance to pitting.
The specific type of stainless steel and its resistance to corrosion depend on its composition and the environment in which it is used. For example, austenitic stainless steels, such as the 300 series, are highly resistant to corrosion and are commonly used in food processing and medical equipment. Ferritic and martensitic stainless steels have different compositions and are used in applications where specific mechanical properties are required.
Overall, the combination of chromium and other alloying elements, along with the formation of a passive oxide layer, enables stainless steel to resist corrosion effectively in a wide range of environments.